Radon adsorption of Cu-imidazole-based metal-organic frameworks
- NázevTitle
- Radon adsorption of Cu-imidazole-based metal-organic frameworksRadon adsorption of Cu-imidazole-based metal-organic frameworks
- PoskytovatelProvider
- Jiný zahraniční poskytovatelAnother foreign provider
- ProgramProgramme
- Projekty podpořené ze zahraničí (pracovní kód k dodatečnému upřesnění)Projekty podpořené ze zahraničí (pracovní kód k dodatečnému upřesnění)
- Kód CEPCEP code
- Datum zahájeníStart date
- 2024-04-01
- Datum ukončeníEnd date
- 2024-12-31
- Vztah ČVUTCTU relation
- ČVUT je v pozici příjemce jako jediný účastník projektuCTU is the only beneficiary participant in the project
- Řešitel ČVUTCTU investigator
- Shefali Vaidya, Ph.D.
AbstraktAbstract
Metal-organic frameworks (MOFs) are a category of 3D materials that consist of metal ions and organic ligands. The subclass of MOFs comprising zinc metal ions and imidazole as an organic ligand, commonly known as zeolitic imidazole frameworks, has been extensively investigated for various applications (e.g. gas and molecular separation, adsorption, catalysis etc.). However, less attention is paid towards copper-imidazole MOFs. Though few structures are reported, their application-based studies have been scarce. Copper-based coordination polymers or MOFs are known to contain copper in a +I or +II oxidation state and redox-active, unlike zinc, which primarily shows a +II oxidation state and is redox inactive. The redox nature of the copper in association with imidazole can be utilized in catalysis. Therefore, the potential applicability of Cu-imidazole-based CPs/MOFs is expected to be higher.
Metal-organic frameworks (MOFs) are a category of 3D materials that consist of metal ions and organic ligands. The subclass of MOFs comprising zinc metal ions and imidazole as an organic ligand, commonly known as zeolitic imidazole frameworks, has been extensively investigated for various applications (e.g. gas and molecular separation, adsorption, catalysis etc.). However, less attention is paid towards copper-imidazole MOFs. Though few structures are reported, their application-based studies have been scarce. Copper-based coordination polymers or MOFs are known to contain copper in a +I or +II oxidation state and redox-active, unlike zinc, which primarily shows a +II oxidation state and is redox inactive. The redox nature of the copper in association with imidazole can be utilized in catalysis. Therefore, the potential applicability of Cu-imidazole-based CPs/MOFs is expected to be higher.