Ústav technické a experimentální fyziky Institute of Experimental and Applied Physics

Sustainable and Efficient Low-Energy Light Emitters: A Series of One-Dimensional d(10) Coinage Metal-Organic Chalcogenolates, [M(o-SPhCO2H)](n)

NázevTitle
Sustainable and Efficient Low-Energy Light Emitters: A Series of One-Dimensional d(10) Coinage Metal-Organic Chalcogenolates, [M(o-SPhCO2H)](n)Sustainable and Efficient Low-Energy Light Emitters: A Series of One-Dimensional d(10) Coinage Metal-Organic Chalcogenolates, [M(o-SPhCO2H)](n)
Druh výsledkuResult type
Článek v časopiseJournal article
AutořiAuthors
O. Veselska, N. Guillou, M. Diaz-Lopez, P. Bordet
DOIDOI
10.1002/cptc.202200030
Časopis / citaceJournal / citation
ChemPhotoChem. 2022, 6(5), ISSN 2367-0932.
RokYear
2022
JazykLanguage
eng
WoSWoS
000764188300001
ScopusScopus
2-s2.0-85125555952
RIVRIV
RIV/68407700:21670/22:00357798!RIV23-MSM-21670___
ProjektProject
Institucionální podpora na rozvoj výzkumné org.Institucionální podpora na rozvoj výzkumné org.

AbstraktAbstract

A series of d(10) coinage metal thiosalicylate coordination polymers (CPs) is reported. The 1D structures of the three CPs are formed by M3S3 fused hexagons for Cu and Ag compounds and interpenetrated helical chains for Au CP. Depending on the metal, solid-state red and NIR emissive CPs are obtained with quantum yields up to 50 %, providing a great opportunity to replace the actual emissive critical raw materials.

A series of d(10) coinage metal thiosalicylate coordination polymers (CPs) is reported. The 1D structures of the three CPs are formed by M3S3 fused hexagons for Cu and Ag compounds and interpenetrated helical chains for Au CP. Depending on the metal, solid-state red and NIR emissive CPs are obtained with quantum yields up to 50 %, providing a great opportunity to replace the actual emissive critical raw materials.