Ústav technické a experimentální fyziky Institute of Experimental and Applied Physics

Effect of the 1D/2D dimensionality in copper and silver thiolate coordination polymers on their photophysical properties

NázevTitle
Effect of the 1D/2D dimensionality in copper and silver thiolate coordination polymers on their photophysical propertiesEffect of the 1D/2D dimensionality in copper and silver thiolate coordination polymers on their photophysical properties
Druh výsledkuResult type
Článek v časopiseJournal article
AutořiAuthors
O. Veselska, A. Abdallah, A. Giraudon
DOIDOI
10.1039/D4CC06171C
Časopis / citaceJournal / citation
Chemical Communications. 2025, 61(5), 977-980. ISSN 1364-548X.
RokYear
2025
JazykLanguage
eng
WoSWoS
001378713700001
ScopusScopus
2-s2.0-85212704153
RIVRIV
RIV/68407700:21670/25:00380376!RIV26-MSM-21670___
ProjektProject
Institucionální podpora na rozvoj výzkumné org.Institucionální podpora na rozvoj výzkumné org.

AbstraktAbstract

A series of four new copper and silver-thiolate, [M(m-SPhCO2R)]n (M = Cu, Ag and R = H, Me), coordination polymers is reported. The study shows that the hydrogen bonding between the carboxylic acids directs the formation of a 2D structure associated with poor photoemission, while the steric hindrance of the ester groups allows the assembly of a 1D network coupled with bright luminescence.

A series of four new copper and silver-thiolate, [M(m-SPhCO2R)]n (M = Cu, Ag and R = H, Me), coordination polymers is reported. The study shows that the hydrogen bonding between the carboxylic acids directs the formation of a 2D structure associated with poor photoemission, while the steric hindrance of the ester groups allows the assembly of a 1D network coupled with bright luminescence.