Effect of the 1D/2D dimensionality in copper and silver thiolate coordination polymers on their photophysical properties
- NázevTitle
- Effect of the 1D/2D dimensionality in copper and silver thiolate coordination polymers on their photophysical propertiesEffect of the 1D/2D dimensionality in copper and silver thiolate coordination polymers on their photophysical properties
- Druh výsledkuResult type
- Článek v časopiseJournal article
- AutořiAuthors
- O. Veselska, A. Abdallah, A. Giraudon
- Klíčová slovaKeywords
- Luminescence, Coordination Polymer, Coinage metals, Thiolates
- DOIDOI
- 10.1039/D4CC06171C
- Časopis / citaceJournal / citation
- Chemical Communications 61(5), 977-980 (2025) · ISSN 1364-548X
- RokYear
- 2025
- JazykLanguage
- eng
- ZáznamyRecords
- ProjektProject
- Institucionální podpora na rozvoj výzkumné org.Institucionální podpora na rozvoj výzkumné org.
- CitovánoCited by
- 6 (OpenAlex)
- Plný text (open access)Full text (open access)
- https://hal.science/hal-04957355/document
- Citace ke staženíDownload citation
- TXT · BibTeX
AbstraktAbstract
A series of four new copper and silver-thiolate, [M(m-SPhCO2R)]n (M = Cu, Ag and R = H, Me), coordination polymers is reported. The study shows that the hydrogen bonding between the carboxylic acids directs the formation of a 2D structure associated with poor photoemission, while the steric hindrance of the ester groups allows the assembly of a 1D network coupled with bright luminescence.
A series of four new copper and silver-thiolate, [M(m-SPhCO2R)]n (M = Cu, Ag and R = H, Me), coordination polymers is reported. The study shows that the hydrogen bonding between the carboxylic acids directs the formation of a 2D structure associated with poor photoemission, while the steric hindrance of the ester groups allows the assembly of a 1D network coupled with bright luminescence.